Category: 79247-77-1

Formula: C4H6Br2N2S. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 5-Bromo-4-methyl-thiazol-2-ylamine hydrobromide, is researched, Molecular C4H6Br2N2S, CAS is 79247-77-1, about An infrared study of rotational isomerism in thiazole-2-carboxylates. Author is Kaye, Perry T.; Meakins, G. Denis; Willbe, Charles; Williams, Peter R..

Twenty-five alkyl thiazole-2-carboxylates with a range of 4- and 5-substituents were prepared through the Hantzsch synthesis. E.g., cyclocondensation reaction of (H2N)2CS with MeCOCH2Br followed by bromination, oxidation, and alkylation gave the thiazole esters I (R = Me, Et). Solutions of these esters show well resolved doublets in the carbonyl IR spectra, due to rotational isomers. The higher wave number components were assigned to the more polar carbonyl O,S-anti-s-trans rotamers and those at lower wave number to the O,S-syn-s-trans forms. Small, but systematic, differences between the Me esters were noted.

If you want to learn more about this compound(5-Bromo-4-methyl-thiazol-2-ylamine hydrobromide)Formula: C4H6Br2N2S, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(79247-77-1).

Reference:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

Kaye, Perry T.; Meakins, G. Denis; Willbe, Charles; Williams, Peter R. published the article 《An infrared study of rotational isomerism in thiazole-2-carboxylates》. Keywords: thiazolecarboxylate IR rotational isomerism; Hantzsch thiourea bromoacetone; bromomethylthiazolecarboxylate ethyl methyl; methylthiazolecarboxylate bromo ethyl methyl; carboxylate thiazole IR rotational isomerism.They researched the compound: 5-Bromo-4-methyl-thiazol-2-ylamine hydrobromide( cas:79247-77-1 ).Category: amides-buliding-blocks. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:79247-77-1) here.

Twenty-five alkyl thiazole-2-carboxylates with a range of 4- and 5-substituents were prepared through the Hantzsch synthesis. E.g., cyclocondensation reaction of (H2N)2CS with MeCOCH2Br followed by bromination, oxidation, and alkylation gave the thiazole esters I (R = Me, Et). Solutions of these esters show well resolved doublets in the carbonyl IR spectra, due to rotational isomers. The higher wave number components were assigned to the more polar carbonyl O,S-anti-s-trans rotamers and those at lower wave number to the O,S-syn-s-trans forms. Small, but systematic, differences between the Me esters were noted.

If you want to learn more about this compound(5-Bromo-4-methyl-thiazol-2-ylamine hydrobromide)Category: amides-buliding-blocks, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(79247-77-1).

Reference:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 5-Bromo-4-methyl-thiazol-2-ylamine hydrobromide(SMILESS: NC1=NC(C)=C(Br)S1.[H]Br,cas:79247-77-1) is researched.SDS of cas: 180258-46-2. The article 《An infrared study of rotational isomerism in thiazole-2-carboxylates》 in relation to this compound, is published in Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999). Let’s take a look at the latest research on this compound (cas:79247-77-1).

Twenty-five alkyl thiazole-2-carboxylates with a range of 4- and 5-substituents were prepared through the Hantzsch synthesis. E.g., cyclocondensation reaction of (H2N)2CS with MeCOCH2Br followed by bromination, oxidation, and alkylation gave the thiazole esters I (R = Me, Et). Solutions of these esters show well resolved doublets in the carbonyl IR spectra, due to rotational isomers. The higher wave number components were assigned to the more polar carbonyl O,S-anti-s-trans rotamers and those at lower wave number to the O,S-syn-s-trans forms. Small, but systematic, differences between the Me esters were noted.

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Reference:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called An infrared study of rotational isomerism in thiazole-2-carboxylates, published in 1981-08-31, which mentions a compound: 79247-77-1, Name is 5-Bromo-4-methyl-thiazol-2-ylamine hydrobromide, Molecular C4H6Br2N2S, Category: amides-buliding-blocks.

Twenty-five alkyl thiazole-2-carboxylates with a range of 4- and 5-substituents were prepared through the Hantzsch synthesis. E.g., cyclocondensation reaction of (H2N)2CS with MeCOCH2Br followed by bromination, oxidation, and alkylation gave the thiazole esters I (R = Me, Et). Solutions of these esters show well resolved doublets in the carbonyl IR spectra, due to rotational isomers. The higher wave number components were assigned to the more polar carbonyl O,S-anti-s-trans rotamers and those at lower wave number to the O,S-syn-s-trans forms. Small, but systematic, differences between the Me esters were noted.

Here is a brief introduction to this compound(79247-77-1)Category: amides-buliding-blocks, if you want to know about other compounds related to this compound(79247-77-1), you can read my other articles.

Reference:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics