Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , Computed Properties of C2H7ClN2O, 1668-10-6, Name is H-Gly-NH2.HCl, molecular formula is C2H7ClN2O, belongs to amides-buliding-blocks compound. In a document, author is Dutta, Devawati, introduce the new discover.
1,8-Bis(borylamido)naphthalene Complexes of Lithium and Zinc(II) Including a Zinc(II) Isocyanide Adduct
The zinc coordination chemistry of a useful metal ion chelator, bis(borylamido)naphthalene ligand [1,8-C10H6(NBNL)(2)](2-), which has two borylamido groups on a rigid naphthalene backbone, is presented. Deprotonation of N-1,N-8-di(9-bora-bicyclo[3.3.1]nonan-9-yl)naphthalene-1,8-diamine, [1,8-C10H6(NBNL)(2)]H-2 (3) with two equivalents of nBuLi in Et2O afforded the lithium derivative, Li-2(Et2O)(2)[1,8-C10H6(NBNL)(2)] (4). Metathesis reaction of Li-2(Et2O)(2)[1,8-C10H6(NBNL)(2)] with (tBu(2)bipy)ZnCl2 (tBu(2)bipy = 4,4-di-tert-butyl-2,2-bipyridine) in a 1:1 molar ratio gave [1,8-C10H6(NBNL)(2)]Zn(tBu(2)bipy) (5), which features an all-nitrogen coordination sphere at zinc. The reaction of 4 with ZnCl2, however, produced [1,8-C10H6(NBNL)(2)]Zn(Et2O)(mu-Cl)Li(Et2O)(3) (6), which retains one of the chlorides as ClLi(Et2O)(3) on zinc. Treatment of 6 with tBu(2)bipy or two equivalents of 2,6-dimethylphenyl isocyanide completes the salt elimination and led to [1,8-C10H6(NBNL)(2)]Zn(tBu(2)bipy) (5) or [1,8-C10H6(NBNL)(2)]Zn(CNC6H3-2,6-Me-2)(2) (7), respectively. Compounds 3-7 have been characterized by several analytical methods including X-ray crystallography. The zinc atoms of 5-7 are four-coordinate and adopt a distorted tetrahedral geometry. The (NC) bands of 7 in the IR spectrum have been observed at 2203 and 2187 cm(-1).
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