Category: 1185-53-1

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Safety of Tris hydrochloride, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1185-53-1, Name is Tris hydrochloride, molecular formula is C4H12ClNO3. In an article, author is Wang, Kai,once mentioned of 1185-53-1.

Iron-catalyzed peroxidation-carbamoylation of alkenes with hydroperoxides and formamides via formyl C(sp(2))-H functionalization

A reaction protocol in which FeCl3 and tert-butyl hydroperoxide facilitated a selective radical coupling reaction of aryl alkenes or 1,3-enynes with tert-butyl hydroperoxide and formamides to prepare an array of beta-peroxy amides has been achieved. The beta-peroxy amide could serve as a synthetic precursor which was facilely converted to beta-hydroxy amide, beta-keto amide and beta-lactam following subsequent chemical transformation.

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1185-53-1, Name is Tris hydrochloride, molecular formula is C4H12ClNO3, belongs to amides-buliding-blocks compound, is a common compound. In a patnet, author is Kruk-Slomka, Marta, once mentioned the new application about 1185-53-1, Recommanded Product: Tris hydrochloride.

Antibacterial Activity of Novel 18 beta-Glycyrrhetinic Hydrazide or Amide Derivatives

Through a facile structural modification on the natural bioactive ingredient 18 beta-glycyrrhetinic acid(GA), a series of novel GA hydrazide or amide derivatives was obtained, and their final molecular frameworks were characterized by NMR and HRMS analysis. Antibacterial bioassays revealed that some of the GA hydrazide or amide derivatives were able to suppress the growth of three tested plant pathogens. Particularly, compound 3c exhibited excellent in vitro activity against Xanthomonas oryzae pv. Oryzae (Xoo), Pseudomonas syringae pv. actinidiae(Psa), and Xanthomonas axonopodis pv. citri(Xac), providing the EC50 values of 5.89, 16.1, and 3.64 mu g/mL, respectively. The data were better than those of the positive controls thiodiazole copper(92.7, 77.8, and 89.9 mu g/mL, respectively) and bismerthiazol(31.1, 125.6, and 77.4 mu g/mL, respectively). In addition, in vivo experiments suggested that, compared with thiodiazole copper(41.93% and 39.73%, respectively), compound 3c exerted prominently curative and protective activities against rice bacterial leaf blight at 200 mu g/mL with the control effects of 52.36% and 51.40%, respectively. Given these obtained results, GA hydrazide or amide derivatives could serve as the feasible leads for exploring highly bioactive substrates.

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