Moglie, Yanina; Buxaderas, Eduardo; Mancini, Agustina; Alonso, Francisco; Radivoy, Gabriel published an article in 2019, the title of the article was Amide Bond Formation Catalyzed by Recyclable Copper Nanoparticles Supported on Zeolite Y under Mild Conditions.Application In Synthesis of N,N-Diethylacetamide And the article contains the following content:
A series of catalysts based on supported copper nanoparticles were prepared and tested in the amide bond formation from tertiary amines and acid anhydrides, in the presence of tert-Bu hydroperoxide as an oxidant. Copper nanoparticles on zeolite Y (CuNPs/ZY) was found to be the most efficient catalyst for the synthesis of amides, working in acetonitrile as solvent, under ligand- and base-free conditions in air. The products were obtained in good to excellent yields and in short reaction times. The CuNPs/ZY system also exhibited higher catalytic activity than some com. available copper and iron sources and it was reused in ten reaction cycles without any further pre-treatment. This methodol. was successfully scaled-up to a gram scale with no detriment to the yield. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Application In Synthesis of N,N-Diethylacetamide
The Article related to reusable zeolite support copper nanoparticle preparation surface area, tertiary amine caboxylic anhydride copper nanocatalyst amidation, aryl alkyl amide preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Application In Synthesis of N,N-Diethylacetamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics