《Palladium-catalyzed carbene coupling of N-tosylhydrazones and arylbromides to synthesize cross-conjugated polymers》 was written by Zhou, Qi; Gao, Yunpeng; Xiao, Yiyang; Yu, Lefei; Fu, Zihao; Li, Zichen; Wang, Jianbo. Formula: C4H9NO2This research focused ontosylhydrazone arylbromide palladium carbene coupling cross conjugated polymer. The article conveys some information:
Carbene-involving cross-coupling reactions of N-tosylhydrazones and arylbromides have been introduced into polymer chem. for the first time, providing a novel method to access a new type of cross-conjugated polymer, poly(arylene-1,1-vinylidene)s (iso-PAVs). The pendant double bonds of these cross-conjugated polymers allow for further post-polymerization functionalization. The good thermal stability and remarkable optical properties of these cross-conjugated polymers reveal their potential for applications. In the part of experimental materials, we found many familiar compounds, such as N-Methoxy-N-methylacetamide(cas: 78191-00-1Formula: C4H9NO2)
N-Methoxy-N-methylacetamide(cas: 78191-00-1) belongs to anime. Hydrogen peroxide (H2O2) and peroxy acids generally add an oxygen atom to the nitrogen of amines. With primary amines, this step is normally followed by further oxidation, leading to nitroso compounds, RNO, or nitro compounds, RNO2. Secondary amines are converted to hydroxylamines, R2NOH, and tertiary amines to amine oxides, R3NO.Formula: C4H9NO2
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics