Hirai, Toshihiro’s team published research in Organic Letters in 2017 | CAS: 71432-55-8

tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8) belongs to anime. Amines have a free lone pair with which they can coordinate to metal centers. Amine–metal bonds are weaker because amines are incapable of backbonding, but they are still important for sensing applications.While stronger than hydrogen bonds, amine–metal bonds are still weaker than both covalent and ionic bonds.SDS of cas: 71432-55-8

In 2017,Hirai, Toshihiro; Shibata, Kohki; Niwano, Yohei; Shiozaki, Masao; Hashimoto, Yoshimitsu; Morita, Nobuyoshi; Ban, Shintaro; Tamura, Osamu published 《Total synthesis of neodysiherbaine A via 1,3-dipolar cycloaddition of a chiral nitrone template》.Organic Letters published the findings.SDS of cas: 71432-55-8 The information in the text is summarized as follows:

The total synthesis of neodysiherbaine A was achieved via 1,3-dipolar cycloaddition of a chiral nitrone template with a sugar-derived allyl alc. in the presence of MgBr2·OEt2. This cycloaddition constructed the C2 and C4 asym. centers in a single step. Then reductive cleavage, intramol. SN2 reaction of the tertiary alc., and oxidation of the primary alc. afforded neodysiherbaine A. In the part of experimental materials, we found many familiar compounds, such as tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8SDS of cas: 71432-55-8)

tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8) belongs to anime. Amines have a free lone pair with which they can coordinate to metal centers. Amine–metal bonds are weaker because amines are incapable of backbonding, but they are still important for sensing applications.While stronger than hydrogen bonds, amine–metal bonds are still weaker than both covalent and ionic bonds.SDS of cas: 71432-55-8

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics