Computed Properties of C11H24N2OIn 2015 ,《Triggering Activity of Catalytic Rod-Like Supramolecular Polymers》 was published in Chemistry – A European Journal. The article was written by Huerta, Elisa; van Genabeek, Bas; Lamers, Brigitte A. G.; Koenigs, Marcel M. E.; Meijer, E. W.; Palmans, Anja R. A.. The article contains the following contents:
Supramol. polymers based on benzene-1,3,5-tricarboxamides (BTAs) functionalized with an L- or D-proline moiety I [R = H, Me; R1 = (S)-3,7-dimethyloctyl, (R)-3,7-dimethyloctyl, n-decane, n-octane] and II [R2 = (R)-3,7-dimethyloctyl] display high catalytic activity toward aldol reactions in water. High turnover frequencies (TOF) of up to 27×10-4 s-1 and excellent stereoselectivities (up to 96 % de, up to 99 % ee) were observed In addition, the catalyst could be reused and remained active at catalyst loadings and substrate concentrations as low as 0.1 mol % and 50 mM, resp. A temperature-induced conformational change in the supramol. polymer triggers the high activity of the catalyst. The supramol. polymer’s helical sense in combination with the configuration of the proline (L- or D-) is responsible for the observed selectivity. In the experiment, the researchers used many compounds, for example, tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8Computed Properties of C11H24N2O)
tert-Butyl N,N’-diisopropylcarbamimidate(cas: 71432-55-8) belongs to anime. Milder oxidation, using reagents such as NaOCl, can remove four hydrogen atoms from primary amines of the type RCH2NH2 to form nitriles (R―C≡N), and oxidation with reagents such as MnO2 can remove two hydrogen atoms from secondary amines (R2CH―NHR′) to form imines (R2C=NR′). Tertiary amines can be oxidized to enamines (R2C=CHNR2) by a variety of reagents.Computed Properties of C11H24N2O
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics