Whalley, David M.; Duong, Hung A.; Greaney, Michael F. published the artcile< Alkene Carboarylation through Catalyst-Free, Visible Light-Mediated Smiles Rearrangement>, Safety of o-Chlorobenzenesulfonamide, the main research area is aliphatic ester preparation carboarylation arenesulfonamide alkene Truce Smiles rearrangement; acetamide preparation tandem photoredox carboarylation Truce Smiles rearrangement; aromatic substitution; arylation; photochemistry; radical reactions; rearrangement.
A light-mediated Truce-Smiles arylative rearrangement is described that proceeds in the absence of any photocatalyst. The protocol creates two C-C bonds from simple starting materials, with the installation of an aryl ring and a difluoroacetate moiety across unactivated alkenes. The reaction proceeds via a radical mechanism, utilizing a light-mediated reduction of Et bromodifluoroacetate by N,N,N’,N’-tetramethylethylenediamine (TMEDA) to set up intermol. addition to an unactivated alkene, followed by Truce-Smiles rearrangement.
Chemistry – A European Journal published new progress about Acetamides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 6961-82-6 belongs to class amides-buliding-blocks, and the molecular formula is C6H6ClNO2S, Safety of o-Chlorobenzenesulfonamide.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics