Chen, Ming; Yang, Chao; Wang, Yanpei; Li, Dazhi; Xia, Wujiong published the artcile< UV Light Induced Direct Synthesis of Phenanthrene Derivatives from a Linear 3-Aryl-N-(arylsulfonyl) Propiolamides>, Formula: C6H6FNO2S, the main research area is phenanthrene preparation UV light induced tandem reaction arylarylsulfonyl propiolamide; photochem radical Smiles rearrangement carbon sulfur bonding Mallory reaction; gram scale reaction flow reactor phenanthrene preparation.
A novel photochem. approach for the synthesis of phenanthrene derivatives from linear 3-aryl-N-(arylsulfonyl) propiolamides via a tandem radical Smiles rearrangement/C-S bonding/Mallory reaction is disclosed. The control experiment results and isolation of the key intermediates give further insight into the reaction mechanism. Gram scale reaction using a flow reactor demonstrated the synthetic potential applications of our protocol.
Organic Letters published new progress about Alkynes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1524-40-9 belongs to class amides-buliding-blocks, and the molecular formula is C6H6FNO2S, Formula: C6H6FNO2S.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics