Gediya, Shweta K.; Vyas, Vijyesh K.; Clarkson, Guy J.; Wills, Martin published the artcile< Asymmetric Transfer Hydrogenation of α-Keto Amides; Highly Enantioselective Formation of Malic Acid Diamides and α-Hydroxyamides>, COA of Formula: C30H31ClN2O2RuS, the main research area is hydroxydiamide regioselective enantioselective preparation; oxodiamide ruthenium chiral diamine catalyst asym transfer hydrogenation; hydroxyamide regioselective enantioselective preparation; oxoamide ruthenium chiral diamine catalyst asym transfer hydrogenation.
The asym. transfer hydrogenation (ATH) of α-keto-1,4-diamides using a tethered Ru/TsDPEN catalyst was achieved in high ee. Studies on derivatives identified the structural elements which led to the highest enantioselectivities in the products. The α-keto-amide reduction products were converted to a range of synthetically valuable derivatives
Organic Letters published new progress about Acetamides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1192620-83-9 belongs to class amides-buliding-blocks, and the molecular formula is C30H31ClN2O2RuS, COA of Formula: C30H31ClN2O2RuS.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics