Deb, S. B.; Gamare, J. S.; Kannan, S.; Drew, M. G. B. published the artcile< Uranyl(VI) and lanthanum(III) thio-diglycolamides complexes: Synthesis and structural studies involving nitrate complexation>, Application of C10H20ClNO, the main research area is thiodiglycolamide preparation complexation uranyl lanthanum nitrate; crystal structure uranyl lanthanum thiodiglycolamide nitrato complex; solvent extraction uranyl cation nitric acid medium thiodiglycolamide ligand.
New tri-functional ligands R2NCOCH2SCH2CONR2 (R = iso-Pr, Bu or iso-butyl) were prepared and characterized. The coordination chem. of these ligands with uranyl and lanthanum(III) nitrates was studied by using the IR, 1H NMR and elemental anal. methods. Structures for [UO2(NO3)2(iPr2NCOCH2SCH2CONiPr2)], [UO2(NO3)2(iBu2NCOCH2SCH2CONiBu2)], [La(NO3)3(iPr2NCOCH2SCH2CONiPr2)2] and [La(NO3)3(iBu2NCOCH2SCH2CONiBu2)2] were determined by single crystal x-ray diffraction. These structures show that the ligand acts as a bidentate chelating ligand and bonds through both the carbamoyl groups to the uranyl and La(III) nitrate groups. Solvent extraction studies show that the ligand can extract the uranyl ion from the HNO3 medium but does not show any ability to extract the Am(III) ion.
Polyhedron published new progress about Crystal structure. 5326-82-9 belongs to class amides-buliding-blocks, and the molecular formula is C10H20ClNO, Application of C10H20ClNO.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics