Application In Synthesis of Diphenylmethanamine. I found the field of Chemistry very interesting. Saw the article Chromium-catalysed efficient N-formylation of amines with a recyclable polyoxometalate-supported green catalyst published in 2021.0, Reprint Addresses Yu, H; Han, S (corresponding author), Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China.; Yu, H; Wei, YG (corresponding author), Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100081, Peoples R China.; Wei, YG (corresponding author), Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China.. The CAS is 91-00-9. Through research, I have a further understanding and discovery of Diphenylmethanamine.
A simple and efficient protocol for the formylation of amines with formic acid, catalyzed by a polyoxometalate-based chromium catalyst, is described. Notably, this method shows excellent activity and chemo-selectivity for the formylation of primary amines; diamines have also been successfully employed. Importantly, the chromium catalyst is potentially non-toxic, environmentally benign and safer than the widely used high valence chromium catalysts such as CrO3 and K2Cr2O7. The catalyst can be recycled several times with a negligible impact on activity. Finally, a plausible mechanism is provided based on the observation of intermediate and control experiments.
Welcome to talk about 91-00-9, If you have any questions, you can contact Dan, DM; Chen, FB; Zhao, WS; Yu, H; Han, S; Wei, YG or send Email.. Application In Synthesis of Diphenylmethanamine
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics