Formula: C13H13N. Recently I am researching about HIGHLY ENANTIOSELECTIVE HYDROGENATION; CATALYTIC ASYMMETRIC DIAMINATION; MESO-AZIRIDINES; MANNICH REACTION; IMINES; AMINOLYSIS; ADDITIONS; ALKENES; DESIGN; LIGAND, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21790332, 21521002, 21772204]; CASChinese Academy of Sciences [QYZDJSSW-SLH023]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Chen, Y; Pan, YX; He, YM; Fan, QH. The CAS is 91-00-9. Through research, I have a further understanding and discovery of Diphenylmethanamine
A highly enantioselective iridium- or ruthenium-catalyzed intermolecular reductive amination/asymmetric hydrogenation relay with 2-quinoline aldehydes and aromatic amines has been developed. A broad range of sterically tunable chiral N,N’-diaryl vicinal diamines were obtained in high yields (up to 95%) with excellent enantioselectivity (up to >99% ee). The resulting chiral diamines could be readily transformed into sterically hindered chiral N-heterocyclic carbene (NHC) precursors, which are otherwise difficult to access. The usefulness of this synthetic approach was further demonstrated by the successful application of one of the chiral vicinal diamines and chiral NHC ligands in a transition-metal-catalyzed asymmetric Suzuki-Miyaura cross-coupling reaction and asymmetric ring-opening cross-metathesis, respectively.
Formula: C13H13N. Bye, fridends, I hope you can learn more about C13H13N, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics