Quality Control of Diphenylmethanamine. In 2019 CHEM-ASIAN J published article about EFFICIENT; OXIDATION; REDUCTION; OXINDOLES; CATALYSTS; AMMONIA; LIQUIDS; CARBON; CO2 in [Guo, Wei-Wei; Zhang, Chi; Ye, Ji-Jie; Liu, Zi-Kun; Chen, Kai; Wu, Chuan-De] Zhejiang Univ, Dept Chem, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China in 2019, Cited 85. The Name is Diphenylmethanamine. Through research, I have a further understanding and discovery of 91-00-9.
Electroorganic synthesis is an environmentally friendly alternative to traditional synthetic methods; however, the application of this strategy is heavily hindered by low product selectivity. Metal-organic frameworks (MOFs) exhibit high selectivity in numerous catalytic reactions; however, poor conductivity heavily limits the application of MOFs in electroorganic synthesis. To realize the electrocatalytic application of MOFs in selective electroorganic synthesis, a practically applicable strategy by suspending ion electrocatalysts in charged MOFs is herein reported. This approach could markedly improve the product selectivity in electroorganic synthesis. In the electrocatalytic oxidative self-coupling of benzylamine experiments, the imine product selectivity is markedly improved from 61.3 to 94.9 %, when the MOF-based electrocatalyst is used instead of the corresponding homogeneous electrocatalyst under the identical conditions. Therefore, this work opens a new route to improve the product selectivity in electroorganic synthesis.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics