In an article, author is Nigiz, Filiz Ugur, once mentioned the application of 536-90-3, Computed Properties of https://www.ambeed.com/products/536-90-3.html, Name is 3-Methoxyaniline, molecular formula is C7H9NO, molecular weight is 123.16, MDL number is MFCD00007783, category is amides-buliding-blocks. Now introduce a scientific discovery about this category.
Treatment of the readily accessible spiro-cyclohexadienones from the PhI(OCOCF3)(2)-mediated spiro-cyclization of N-substituted benzanilides, with BF3 center dot Et2O initiates a tandem ring opening/closure reaction leading to the formation of the biologically interesting 8-hydroxy-phenanthridin-6(5H)-one compounds. This unique rearrangement pattern involves the ‘migration’ of the electron-deficient N-methyl carbamoyl moiety rather than the electron-rich aryl group as observed and reported previously in all other similar transformations.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics