A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Quality Control of Trimethylamine hydrochloride, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 593-81-7, Name is Trimethylamine hydrochloride, molecular formula is C3H10ClN. In an article, author is Sauermann, Nicolas,once mentioned of 593-81-7.
The development of a strategy for remote C7-H functionalizations of the naphthalene rings is greatly challenging. Disclosed herein is an example of direct and regioselective arylation of the naphthalene rings at the C7 position that is promoted by F+ reagents. This protocol features good tolerance of reactive functional groups, mild reaction conditions, and simple reaction system. By control experiments, a kinetic isotope effect (KIE) experiment, and NMR experiments, the mechanistic pathway involving a carbopalladation/aryl migration has been illustrated clearly. Beyond the simple directing function, the sterically hindered N-(t-butyl)amide plays an important role in the regioselectivity control via a carbopalladation/aryl migration.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics