Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 52-89-1, Name is H-Cys-OH.HCl, SMILES is N[C@@H](CS)C(O)=O.[H]Cl, in an article , author is Wang, Chaorong, once mentioned of 52-89-1, Formula: https://www.ambeed.com/products/52-89-1.html.
An atom economical approach for the synthesis of alpha-carbolin-4-ones has been developed. This process was realized via a C-N bond cleavage/intramolecular amination cascade. During this process, one C-N and one C-C bond are cleaved and two C-N and two C-C bonds are formed. Mechanistic studies suggested a migrative N-cyclization process involving a carbene intermediate.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics