Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 598-50-5, Name is 1-Methylurea, molecular formula is C2H6N2O, belongs to amides-buliding-blocks compound. In a document, author is Yu, Sheng-Sheng, introduce the new discover, Product Details of 598-50-5.
The metal-catalyzed dehydrogenative coupling of alcohols and amines to access amides has been recognized as an atom-economic and environmental-friendly process. Apart from the formation of the amide products, three other kinds of compounds (esters, imines and amines) may also be produced. Therefore, it is of vital importance to investigate product distribution in this transformation. Herein, N-heterocyclic carbene-based Ru (NHC/Ru) complexes [Ru-1]-[Ru-5] with different ancillary ligands were prepared and characterized. Based on these complexes, we selected condition A (without an added NHC precursor) and condition B (with an added NHC precursor) to comprehensively explore the selectivity and yield of the desired amides. After careful evaluation of various parameters, the Ru loadings, added NHC precursors and the electronic/steric properties of ancillary NHC ligands were found to have considerable influence on this catalytic process. (C) 2020 Elsevier Ltd. All rights reserved.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 598-50-5. Product Details of 598-50-5.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics