Related Products of 62-57-7, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 62-57-7, Name is H-Aib-OH, SMILES is CC(C(O)=O)(C)N, belongs to amides-buliding-blocks compound. In a article, author is Yang, Hongbin, introduce new discover of the category.
Intermolecular C-C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent ‘ene’-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer complex that forms between an alkene, alpha-chloroamide, and flavin hydroquinone. This unique mechanism ensures that radical formation only occurs when both substrates are present within the protein active site. This active site can control the radical terminating hydrogen atom transfer, enabling the synthesis of enantioenriched gamma-stereogenic amides. This work highlights the potential for photoenzymatic catalysis to enable new biocatalytic transformations via previously unknown electron transfer mechanisms.
Related Products of 62-57-7, One of the oldest and most widely used commercial enzyme inhibitors is aspirin, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. you can also check out more blogs about 62-57-7.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics