Related Products of 114457-94-2, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential. 114457-94-2, Name is (S)-3-Phenyl-2-(pyrazine-2-carboxamido)propanoic acid, SMILES is O=C(O)[C@@H](NC(C1=NC=CN=C1)=O)CC2=CC=CC=C2, belongs to amides-buliding-blocks compound. In a article, author is Jalalvandi, Esmat, introduce new discover of the category.
Facile synthesis of unnatural -germyl–amino amides via Pd(ii)-catalyzed primary and secondary C(sp(3))-H bond germylation
Pd(ii)-Catalyzed direct C(sp(3))-H germylation of -AA derivatives with the assistance of a bidentate auxiliary for the efficient synthesis of -germyl–amino amides is reported. This protocol features good generality for primary and secondary C-H bonds of aliphatic amides. Mechanistic studies show that a crucial five-membered palladacycle intermediate may play a key role in this process.
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