Top Picks: new discover of 1638767-25-5

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Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Gao, Hongwei, once mentioned the application of 1638767-25-5, Name is tert-Butyl (3-aminobicyclo[1.1.1]pentan-1-yl)carbamate, molecular formula is C10H18N2O2, molecular weight is 198.2621, MDL number is MFCD27987307, category is amides-buliding-blocks. Now introduce a scientific discovery about this category, COA of Formula: C10H18N2O2.

Half-sandwich ruthenium-carbene catalysts: Synthesis, characterization, and catalytic application in the N-alkylation of amines with alcohols

In this study, the synthesis and characterization of new half-sandwich ruthenium complexes containing oxygen functionalised N-aryl and N-alkyl benzimidazol-2-ylidene ligands have been reported. All ruthenium complexes were tested as catalysts for a wide range of substrates in the N-alkylation of secondary cyclic amines such as pyrrolidine and piperidine, and 4-methylaniline which was a primary aromatic amine with alcohols by hydrogen-borrowing process. The catalytic reactions were performed with 1 mol% catalyst loading at 120 degrees C, 16 h under solvent-free conditions. All ruthenium complexes showed excellent catalytic activity, and N-alkylated products were obtained selectively.

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