The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 7396-58-9, Name is N-Decyl-N-methyldecan-1-amine, SMILES is CN(CCCCCCCCCC)CCCCCCCCCC, in an article , author is Chen, Jinfeng, once mentioned of 7396-58-9, Safety of N-Decyl-N-methyldecan-1-amine.
Transition-Metal-Free Activation of Amides by N-C Bond Cleavage
The amide bond N-C activation represents a powerful strategy in organic synthesis to functionalize the historically inert amide linkage. This personal account highlights recent remarkable advances in transition-metal-free activation of amides by N-C bond cleavage, focusing on both (1) mechanistic aspects of ground-state-destabilization of the amide bond enabling formation of tetrahedral intermediates directly from amides with unprecedented selectivity, and (2) synthetic utility of the developed transformations. Direct nucleophilic addition to amides enables a myriad of powerful methods for the formation of C-C, C-N, C-O and C-S bonds, providing a straightforward and more synthetically useful alternative to acyl-metals.
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