34381-71-0, Name is (S)-(-)-1-Methyl-2-pyrrolidinemethanol, molecular formula is C6H13NO, belongs to amides-buliding-blocks compound, is a common compound. In a patnet, author is Zhang Xinming, once mentioned the new application about 34381-71-0, Recommanded Product: 34381-71-0.
Cyclobutane-based peptides/terpyridine conjugates: Their use in metal catalysis and as functional organogelators
Two new conjugates, hcptpyDP and hcptpyTP, of a terpyridine derivative incorporating artificial peptide moieties, have been synthesized and their use in the preparation of metal catalysts and organogelators has been investigated. Ru(II) complexes derived from these ligands showed electrochemical behavior and activity as catalysts in the epoxidation of olefins similar to that of Beller’s catalyst. As organogelators, these conjugates were able to gelate a variety of solvents, from toluene to methanol, with satisfactory mgc (minimum gelation concentration) values. The presence of 4′-(4-carboxy)phenylterpyridine (hcptpy) moiety allows tuning the gelling properties and also influences the supramolecular self-assembling mode to produce chiral aggregates with respect to parent peptides DP and TP. In the case of the conjugates, pi-pi interactions provided by the aromatic moieties cooperate with inter-molecular hydrogen bonding between NH and CO in the amide groups. Further properties of peptide/terpyridine conjugates are under investigation in view of future applications. (C) 2018 Elsevier Ltd. All rights reserved.
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