Reference of 683-57-8, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 683-57-8, Name is 2-Bromoacetamide, SMILES is O=C(N)CBr, belongs to amides-buliding-blocks compound. In a article, author is Sletten, Eric T., introduce new discover of the category.
Synthesis of 2-Oxazolines from Ring Opening Isomerization of 3-Amido-2-Phenyl Azetidines
Chiral 2-oxazolines are valuable building blocks and famous ligands for asymmetric catalysis. The most common synthesis involves the reaction of an amino alcohol with a carboxylic acid. In this paper, an efficient synthesis of 2-oxazolines has been achieved via the stereospecific isomerization of 3-amido-2-phenyl azetidines. The reactions were studied in the presence of both Bronsted and Lewis acids, and Cu(OTf)(2) was found to be the most effective.
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