In an article, author is Ning, Xibo, once mentioned the application of 25197-96-0, Name: (S)-2-Amino-3-(5-methoxy-1H-indol-3-yl)propanoic acid, Name is (S)-2-Amino-3-(5-methoxy-1H-indol-3-yl)propanoic acid, molecular formula is C12H14N2O3, molecular weight is 234.25, MDL number is MFCD01074513, category is amides-buliding-blocks. Now introduce a scientific discovery about this category.
Iridium-Catalyzed Regio- and Enantioselective Borylation of Unbiased Methylene C(sp(3))-H Bonds at the Position beta to a Nitrogen Center
Reported herein is the pyrazole-directed iridium-catalyzed enantioselective borylation of unbiased methylene C-H bonds at the position beta to a nitrogen center. The combination of a chiral bidentate boryl ligand, iridium precursor, and pyrazole directing group was responsible for the high regio- and enantioselectivity observed. The method tolerated a vast array of functional groups to afford the corresponding C(sp(3))-H functionalization products with good to excellent enantioselectivity.
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