Electric Literature of 61-90-5, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 61-90-5, Name is H-Leu-OH, SMILES is CC(C)C[C@H](N)C(O)=O, belongs to amides-buliding-blocks compound. In a article, author is Ding, Sheng, introduce new discover of the category.
Intermolecular interactions in the crystal structures of chlorogold(I) complexes with N-phosphinoamide ligands
[AuCl{RC(O)NHPPh2-kappa P}]gold(I) complexes with varying amide substituents (R = Me, Ph and ferrocenyl) were prepared, characterized by elemental analysis and spectroscopic methods (mass spectrometry and multinuclear NMR and IR spectroscopy) and further studied by single-crystal X-ray crystallography with a particular focus on solid-state interactions. In all cases, the crystal assembly was based mainly on conventional hydrogen bonds between the amide moieties. However, while in chloroform-solvated [AuCl{MeC(O)NHPPh2-kappa P}], these interactions were supported by pi center dot center dot center dot pi stacking of aromatic rings, in the crystal structures of the complexes bearing phenyl and ferrocenyl substituents, they cooperated with aurophilic interactions of the Au(I) centers, which in turn affected the C = O center dot center dot center dot HN hydrogen bonds.
Electric Literature of 61-90-5, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 61-90-5 is helpful to your research.