Xu-Xu, Qing-Feng published the artcileSynthesis of Benzoisoselenazolones via Rh(III)-Catalyzed Direct Annulative Selenation by Using Elemental Selenium, Recommanded Product: (3R,4R,5S,6R)-6-(Acetoxymethyl)-3-benzamidotetrahydro-2H-pyran-2,4,5-triyl triacetate, the publication is Chemistry – A European Journal (2021), 27(71), 17952-17959, database is CAplus and MEDLINE.
In this manuscript, a rhodium-catalyzed direct selenium annulation by using stable and tractable elemental selenium was introduced. A series of benzamides as well as acrylamides RNHC(O)R1 (R = Me, cyclohexyl, Bn, etc.; R1 = prop-1-en-2-yl, Ph, thiophen-2-yl, etc.) were successfully coupled with selenium under mild reaction conditions, and the obtained isoselenazolones I (R2 = H, Me, Ph, Cl; R3 = H, Me, OMe, Cl; R4 = H, OMe, Br, F; R5 = H, Me, OMe, Cl) and II (R6 = Me, Ph; R7 = H; R6R7 = -SCH=CH-) could be pivotal synthetic precursors for several organoselenium compounds e.g., III. Based on the designed control experiments and X-ray absorption spectroscopy measurements, an unprecedented selenation mechanism involving a highly electrophilic Se(IV) species as the reactive selenium donor was proposed. The reaction mechanism was further verified by a computational study.
Chemistry – A European Journal published new progress about 14086-92-1. 14086-92-1 belongs to amides-buliding-blocks, auxiliary class Sugar Units,Glu, name is (3R,4R,5S,6R)-6-(Acetoxymethyl)-3-benzamidotetrahydro-2H-pyran-2,4,5-triyl triacetate, and the molecular formula is C9H13NO2, Recommanded Product: (3R,4R,5S,6R)-6-(Acetoxymethyl)-3-benzamidotetrahydro-2H-pyran-2,4,5-triyl triacetate.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics