Rebstock, Anne-Sophie published the artcileSynthesis and deprotonation of 2-(pyridyl)phenols and 2-(pyridyl)anilines, SDS of cas: 146140-95-6, the publication is Organic & Biomolecular Chemistry (2003), 1(17), 3064-3068, database is CAplus and MEDLINE.
2-(2- And 3-Pyridyl)anilines, 2,2-dimethyl-N-[2-(2- and 3-pyridyl)phenyl]propanamides, and 2-, 3- and 4-(2-methoxyphenyl)pyridines are readily synthesized using cross-coupling reactions. Whereas 2-(3-pyridinyl)benzenamine and 2-(2-pyridinyl)benzenamine undergo side reactions, the corresponding 2,2-dimethyl-N-[2-(2-pyridinyl)phenyl]propanamide and 2,2-dimethyl-N-[2-(3-pyridinyl)phenyl]propanamide (amides) are deprotonated with lithium 2,2,6,6-tetramethylpiperidide. When 2-(2-methoxyphenyl)pyridine (ether) is subjected to the same reagent, lithiation occurs at C6′.
Organic & Biomolecular Chemistry published new progress about 146140-95-6. 146140-95-6 belongs to amides-buliding-blocks, auxiliary class Boronic acid and ester,Amine,Benzene,Amide,Boronic Acids,Boronic Acids,Boronic acid and ester,, name is (2-Pivalamidophenyl)boronic acid, and the molecular formula is C11H16BNO3, SDS of cas: 146140-95-6.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics