Giurg, M. published the artcileHydrogen peroxide oxidation of N,N-dimethylhydrazones promoted by selenium compounds, titanosilicalites or acetonitrile, Application of 2,4-Dichlorobenzamide, the publication is Polish Journal of Chemistry (2002), 76(12), 1713-1720, database is CAplus.
Hydrogen peroxide oxidation of aldehyde dimethylhydrazones promoted by the title reagents has been investigated. Depending on the substrate, nitriles or amides were obatined as the major products accompanied by carboxylic acids and aldehydes. Formation of nitriles using H2O2 in acetonitrile without base is limited to electron-rich substrates. Reaction of electron-deficient dimethylhydrazones with hydrogen peroxide and aqueous sodium carbonate in acetonitrile/water gives amides as the major products. Aliphatic, unsaturated and aromatic nitriles are prepared by the oxidation of the corresponding aldehyde dimethylhydrazones with hydrogen peroxide in the presence of poly(bis-9,10-anthracenyl) diselenide (PADS) as a catalyst. A mechanism for the oxidation of N,N-dimethylhydrazones is proposed; peroxyiminoacetic acid is suggested as the active oxidant in situ.
Polish Journal of Chemistry published new progress about 2447-79-2. 2447-79-2 belongs to amides-buliding-blocks, auxiliary class Chloride,Amine,Benzene,Amide, name is 2,4-Dichlorobenzamide, and the molecular formula is C7H5Cl2NO, Application of 2,4-Dichlorobenzamide.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics