Schroth, Werner’s team published research in Synthesis in | CAS: 14294-10-1

Synthesis published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C5H10N2OS, Related Products of amides-buliding-blocks.

Schroth, Werner published the artcile1,3-Thiazine syntheses with β-diketones via enol phosphate, Related Products of amides-buliding-blocks, the publication is Synthesis (1983), 827-30, database is CAplus.

RCOCH2COR (R = Ph; 4-MeOC6H4, Me) were successively treated with Na or NaOMe, then (PhO)2P(O)Cl in C6H6 or Et2O to give 58-75% RCOCH:CROP(O)(OPh)2 which were cyclized with H2NC(S)R1 (R1 = Ph, Me, CMe3, SEt, NH2, NMe2, morpholino, PhCH:NNH, MeEtC:NNH, 4-MeC6H4SO2NHNH, 4-MeOC6H4) in AcOH containing POCl3, with dropwise addition of 70% HClO4 to give 39-97% thiazinium perchlorates I.

Synthesis published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C5H10N2OS, Related Products of amides-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics