Gompper, Rudolf’s team published research in Synthesis in | CAS: 14294-10-1

Synthesis published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C5H10N2OS, SDS of cas: 14294-10-1.

Gompper, Rudolf published the artcile2,4-Bis(dialkylamino)-5-ethylidene-4,5-dihydro-1,3-thiazole and 2,4-bis(dimethylamino)-5-vinyl-1,3-thiazole, SDS of cas: 14294-10-1, the publication is Synthesis (1981), 647-8, database is CAplus.

Reaction of Me2NCR:NCSR1 (I; R = R1 = Me2N; R = H, R1 = morpholino) with BrCH2CH:CH2 gave an azavinaminidinium salt which upon treatment with NaNH2/NH3 or KOCMe3 gave the ethylidenethiazolines II, which upon heating or treatment with 4-MeC6H4SO3H rearranged to III. Reaction of the azavinamidinium salt from I (R = R1 = NMe2) with NaH in THF gave IV (R2 = H), which upon reaction with HBF4 gave II.HBF4 (R = H, R1 = NMe2) and with PhNCS gave IV (R2 = PhNHCS).

Synthesis published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C5H10N2OS, SDS of cas: 14294-10-1.

Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics