Younis, Osama published the artcileSolid-State Luminescent Materials Containing Both Indole and Pyrimidine Moieties: Design, Synthesis, and Density Functional Theory Calculations, Recommanded Product: 2-Chloroacetamide, the publication is ACS Omega (2022), 7(17), 15016-15026, database is CAplus and MEDLINE.
Heterocyclic compounds with effective solid-state luminescence offer a wide range of uses. It has been observed that combining pyrimidine and indole moieties in a single mol. can enhance material behavior dramatically. Here, different heterocyclic compounds with indole and pyrimidine moieties have been synthesized effectively, and their structures have been validated using NMR, IR, and mass spectroscopy. The photoluminescence behavior of two substances was investigated in powder form and solutions of varying concentrations After aggregation, one mol. displayed a red shifted luminescence spectrum, whereas another homolog showed a blueshift. Thus, d. functional theory calculations were carried out to establish that introducing a terminal group allows modifying of the luminescence behavior by altering the mol. packing. Because of the non-planarity, intermol. interactions, and tiny intermol. distances within the dimers, the materials demonstrated a good emission quantum yield (Φem) in the solid state (ex. 25.6%). At high temperatures, the compounds also demonstrated a stable emission characteristic.
ACS Omega published new progress about 79-07-2. 79-07-2 belongs to amides-buliding-blocks, auxiliary class Chloride,Amine,Aliphatic hydrocarbon chain,Amide,Inhibitor, name is 2-Chloroacetamide, and the molecular formula is C9H8BNO2, Recommanded Product: 2-Chloroacetamide.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics