Arzel, Erwan published the artcileFirst total synthesis of cryptomisrine, SDS of cas: 146140-95-6, the publication is Tetrahedron (1999), 55(41), 12149-12156, database is CAplus.
The first total synthesis of cryptomisrine, a novel indolo[3,2-b]quinoline dimeric alkaloid from Cryptolepis sanguinolenta, is reported. The approach is based on a convergent methodol. which involves a new halogen-dance reaction in 3-fluoro-4-iodoquinoline followed by its cross-coupling reaction to give bis-2-iodo-3-fluoroquinolin-4-ylmethanol which couples with 2-pivaloylaminophenylboronic acid and then heterocyclizes to cryptomisrine.
Tetrahedron published new progress about 146140-95-6. 146140-95-6 belongs to amides-buliding-blocks, auxiliary class Boronic acid and ester,Amine,Benzene,Amide,Boronic Acids,Boronic Acids,Boronic acid and ester,, name is (2-Pivalamidophenyl)boronic acid, and the molecular formula is C11H16BNO3, SDS of cas: 146140-95-6.
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