Four-step spin-crossover in an oxamide-decorated metal-organic framework was written by Wu, Siguo;Bala, Sukhen;Ruan, Zeyu;Huang, Guozhang;Ni, Zhaoping;Tong, Mingliang. And the article was included in Chinese Chemical Letters in 2022.COA of Formula: C12H10N4O2 The following contents are mentioned in the article:
Spin-crossover (SCO) complexes with multiple spin states are promising candidates for high-order magnetic storage and multiple switches. Here, by employing the N,N’-4-dipyridyloxalamide (dpo) ligand, the authors synthesize two Hofmann-type metal-organic frameworks (MOFs) [Fe(dpo){Ag(CN)2}2]·3DMF (1) and [Fe(dpo){Ag(CN)2}2]·0.5MeCN·2DEF (2), which exhibit guest dependent four-step SCO behaviors with the sequences of LS → approx. LS2/3HS1/3 → LS1/2HS1/2 → approx. LS3/10HS7/10 → HS and LS → approx. LS2/3HS1/3 → LS1/2HS1/2 → approx. LS1/4HS3/4 → HS, resp. Therefore, the incorporation of hydrogen-donating/hydrogen-accepting groups into the Hofmann-type MOFs may effectively explore the multi-step SCO materials by tuning hydrogen-bonding interactions. This study involved multiple reactions and reactants, such as N1,N2-Di(pyridin-4-yl)oxalamide (cas: 53118-43-7COA of Formula: C12H10N4O2).
N1,N2-Di(pyridin-4-yl)oxalamide (cas: 53118-43-7) belongs to amides. In primary and secondary amides, the presence of N–H dipoles allows amides to function as H-bond donors as well. Thus amides can participate in hydrogen bonding with water and other protic solvents; the oxygen atom can accept hydrogen bonds from water and the N–H hydrogen atoms can donate H-bonds. The presence of the amide group –C(=O)N– is generally easily established, at least in small molecules. It can be distinguished from nitro and cyano groups in IR spectra. Amides exhibit a moderately intense νCO band near 1650 cm−1. By 1H NMR spectroscopy, CONHR signals occur at low fields. In X-ray crystallography, the C(=O)N center together with the three immediately adjacent atoms characteristically define a plane.COA of Formula: C12H10N4O2
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics