Zhou, Yue published the artcileEnhancing CO2 Electrocatalysis on 2D Porphyrin-Based Metal-Organic Framework Nanosheets Coupled with Visible-Light, Formula: C2H5NO, the main research area is carbon dioxide electrocatalysis porphyrin MOF nanosheet visible light; 2D nanosheets; carbon dioxide reduction; photocoupled electrocatalysis; porphyrin; visualized channels.
2D Catalysts combined with single atom sites are promising candidates to promote CO2 reduction performance, but the ability to target stable materials with distinct structure still remains challenging. Herein, a series of single metal atoms anchored 2D metal-organic framework nanosheets (MOF-NS-M) with visualized and well-ordered mesoporous structures are fabricated and exhibit enhanced CO2 reduction activity and selectivity with the assistance of visible-light. Encouragingly, the CO Faradaic efficiency of MOF-NS-Co exceeds 90% in a wide potential window of -0.5 to -1.0 V vs. RHE and reaches 98.7% with 100 mV pos. shift compared with the result measured under dark. The catalytic kinetics studies show a fast initial electron transfer to CO2 to form *COO-, thanks to the sufficient exposed active sites resulting from the nanosheet nature and adjusted electron transfer pathway caused by the porphyrin photoswitch.
Small Methods published new progress about Adsorption. 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Formula: C2H5NO.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics