FeIII-Catalyzed Synthesis of Primary Amides from Aldehydes was written by Gowda, Ravikumar R.;Chakraborty, Debashis. And the article was included in European Journal of Organic Chemistry in 2011.Category: amides-buliding-blocks This article mentions the following:
A direct synthetic route for the transformation of aldehydes into primary amides in the presence of catalytic amounts of FeCl3 in water is described. Hydroxylamine hydrochloride acts as the nitrogen source in this transformation, and reaction kinetics are investigated. The application of the methodol. to
3,4-Dichlorobenzamide (cas: 2670-38-4) belongs to amides. The amide group is called a peptide bond when it is part of the main chain of a protein, and an isopeptide bond when it occurs in a side chain, such as in the amino acids asparagine and glutamine. The presence of the amide group –C(=O)N– is generally easily established, at least in small molecules. It can be distinguished from nitro and cyano groups in IR spectra. Amides exhibit a moderately intense νCO band near 1650 cm−1. By 1H NMR spectroscopy, CONHR signals occur at low fields. In X-ray crystallography, the C(=O)N center together with the three immediately adjacent atoms characteristically define a plane.Category: amides-buliding-blocks
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics