Graczyk, Julita et al. published their research in Bromatologia i Chemia Toksykologiczna in 1980 | CAS: 7413-34-5

Sodium (S)-2-(4-(((2,4-diaminopteridin-6-yl)methyl)(methyl)amino)benzamido)pentanedioate (cas: 7413-34-5) belongs to amides. Amides are pervasive in nature and technology. Proteins and important plastics like Nylons, Aramid, Twaron, and Kevlar are polymers whose units are connected by amide groups (polyamides); these linkages are easily formed, confer structural rigidity, and resist hydrolysis. Amides are not in general accessible by the direct condensation of amines with carboxylic acids for two reasons: first, both components are readily deactivated by a transfer of a proton from the acid to the amine and second, the hydroxy unit on the carbonyl of the acid is a relatively poor leaving group. Nevertheless, the formation of five- and six-membered rings is often surprisingly simple provided that other factors can be brought into play to assist in the condensation.Synthetic Route of C20H20N8Na2O5

Acute toxicity of methotrexate and cyclophosphamide in underfed mice was written by Graczyk, Julita. And the article was included in Bromatologia i Chemia Toksykologiczna in 1980.Synthetic Route of C20H20N8Na2O5 This article mentions the following:

The i.p. LD50 values of Na methotrexate (I Na salt) [7413-34-5] and cyclophosphamide (II) [50-18-0] in mice fed normal diets were 122 and 460 mg/kg, resp. In animals maintained on 10 and 4% protein diets, the toxicity of I was increased by 3.5- and 20-fold, resp., and that of II was increased by 4- and 8-fold, resp. At LD10 doses, I and II decreased serum total proteins levels in mice on normal diets from 72.3 to 49.1 and 46.8 g/dm3, resp. The latter result may possibly explain the enhancement of I and II toxicity by protein-deficient diets. In the experiment, the researchers used many compounds, for example, Sodium (S)-2-(4-(((2,4-diaminopteridin-6-yl)methyl)(methyl)amino)benzamido)pentanedioate (cas: 7413-34-5Synthetic Route of C20H20N8Na2O5).

Sodium (S)-2-(4-(((2,4-diaminopteridin-6-yl)methyl)(methyl)amino)benzamido)pentanedioate (cas: 7413-34-5) belongs to amides. Amides are pervasive in nature and technology. Proteins and important plastics like Nylons, Aramid, Twaron, and Kevlar are polymers whose units are connected by amide groups (polyamides); these linkages are easily formed, confer structural rigidity, and resist hydrolysis. Amides are not in general accessible by the direct condensation of amines with carboxylic acids for two reasons: first, both components are readily deactivated by a transfer of a proton from the acid to the amine and second, the hydroxy unit on the carbonyl of the acid is a relatively poor leaving group. Nevertheless, the formation of five- and six-membered rings is often surprisingly simple provided that other factors can be brought into play to assist in the condensation.Synthetic Route of C20H20N8Na2O5

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics