Schmidt, Joachim published the artcileBasic hydrolysis of N-alkyltrifluoroacetamides in 50% ethanol. Are these reactions suitable for determining steric substituent constants?, Category: amides-buliding-blocks, the publication is Wissenschaftliche Zeitschrift der Paedagogischen Hochschule Karl Liebknecht Potsdam (1987), 31(1), 23-31, database is CAplus.
The velocity constants for the second-order basic hydrolysis of CF3CONRR1 [R = Me, Et, Pr, Me2CH, Bu, Me2CHCH2, Me(CH2)n (n = 4, 5, 6, 7), Me2CHCH2CH2, Me3C, R1 = H (I); R = R1 = H, Me, Et, Pr] in 50% aqueous EtOH, determined at ≤75% reaction, had good LFER with Charton υ(OR) or υ(NHR) steric constants The extensive deprotonation of I was kinetically characterized.
Wissenschaftliche Zeitschrift der Paedagogischen Hochschule Karl Liebknecht Potsdam published new progress about 360-92-9. 360-92-9 belongs to amides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Amine,Aliphatic hydrocarbon chain,Amide, name is N,N-Diethyl-2,2,2-trifluoroacetamide, and the molecular formula is C6H10F3NO, Category: amides-buliding-blocks.
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