Zhang, Lijun published the artcileCannizzaro-Type Disproportionation of Aromatic Aldehydes to Amides and Alcohols by Using Either a Stoichiometric Amount or a Catalytic Amount of Lanthanide Compounds, Recommanded Product: 2,4-Dichlorobenzamide, the publication is Journal of Organic Chemistry (2006), 71(8), 3149-3153, database is CAplus and MEDLINE.
Aromatic aldehydes can be directly converted to the corresponding amides and alcs. in good to excellent yields by treatment with LiN(SiMe3)2 in the presence of catalytic lanthanide chlorides LnCl3 or with a stoichiometric amount of lanthanide amides [(Me3Si)2N]3Ln(μ-Cl)Li(THF)3 at ambient temperature. The effects of solvents, substituents on the Ph ring, and lanthanide metals on the reaction have been examined The mechanism of the disproportionation reaction was proposed based on the exptl. results.
Journal of Organic Chemistry published new progress about 2447-79-2. 2447-79-2 belongs to amides-buliding-blocks, auxiliary class Chloride,Amine,Benzene,Amide, name is 2,4-Dichlorobenzamide, and the molecular formula is C5H10O2S, Recommanded Product: 2,4-Dichlorobenzamide.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics