Tong, Peng published the artcileHydration of Nitriles to Amides by Thiolate-Bridged Diiron Complexes, Category: amides-buliding-blocks, the publication is Organometallics (2015), 34(14), 3571-3576, database is CAplus.
A series of nitrile-coordinating complexes [Cp*Fe(μ-SEt)RCN]2[PF6]2 (1, R = alkyl, aryl, vinyl, amine) have been obtained by the reaction of [Cp*Fe(μ-SEt)MeCN]2[PF6]2 (1a) with various nitriles in acetone. Complexes 1 can realize the hydration of a nitrile ligand under ambient conditions. Complexes [Cp*Fe(μ-SEt)2(μ-η1:η1-NH(O)CR)FeCp*][PF6] (2) were successfully isolated as intermediates during the hydration process, with 2b and 2e (R = CH2:CH and Et2N) being characterized by spectrometry and X-ray crystallog. Treatment of 2 with HBF4·Et2O in the presence of nitriles released corresponding amides 3. At the same time, the structural features of the [Fe2S2] scaffold were retained. These results confirmed that the hydration of nitriles was realized by cooperative interaction on diiron centers.
Organometallics published new progress about 2451-91-4. 2451-91-4 belongs to amides-buliding-blocks, auxiliary class Nitrile,Amine,Benzene, name is N,N-Dibenzylcyanamide, and the molecular formula is C18H24N6O6S4, Category: amides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics