Premkumar, Muniyappan published the artcileHalf-sandwich Ruthenium(II) Schiff base complexes: Synthesis, characterization and effective catalysts for one-pot conversion of aldehydes to amides, SDS of cas: 2447-79-2, the publication is Journal of Organometallic Chemistry (2019), 120964, database is CAplus.
Five new Schiff base ligands and conformationally rigid half-sandwich organo ruthenium(II) Schiff base complexes (1–5) with the general formula [Ru(η6-p-cymene)(Cl)(L1-5)] (where, L = mono anionic Schiff base ligands) have been synthesized from the reaction of [{(η6-p-cymene)RuCl}2(μ-Cl)2] with a bidentate Schiff bases ligands. These ruthenium(II) Schiff base complexes were fully characterized by elemental anal., FT-IR, UV-Vis, 1H & 13C NMR and mass spectroscopy studies. In chloroform solution, all the metal complexes exhibit characteristic metal to ligand charge transfer bands (MLCT) and emission bands in the visible region. The crystal structure of the complexes [Ru(η6-p-cymene)(Cl)(L1)] (1) and [Ru(η6-p-cymene)(Cl)(L3)] (3) were determined by single crystal x-ray crystallog. The complexes exhibited good catalytic activity for aldehydes to amides by one-pot conversion process in the presence of NaHCO3/NH2OH·HCl.
Journal of Organometallic Chemistry published new progress about 2447-79-2. 2447-79-2 belongs to amides-buliding-blocks, auxiliary class Chloride,Amine,Benzene,Amide, name is 2,4-Dichlorobenzamide, and the molecular formula is C7H5Cl2NO, SDS of cas: 2447-79-2.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics