Thorat, Kishor G. published the artcileModulating TICT to ICT characteristics of acid switchable red emitting boradiazaindacene chromophores: Perspectives from synthesis, photophysical, hyperpolarizability and TD-DFT studies, Quality Control of 14294-10-1, the publication is Dyes and Pigments (2017), 321-334, database is CAplus.
Two new red emitting difluoro-boradiazaindacene fluorophores were synthesized, and their photophys. and hyperpolarizability properties in various microenvironments were evaluated exptl. and characterized in detail with respect to DFT and TD-DFT using B3LYP/6-31G(d) level of theory. The dyes possess reasonable first order hyperpolarizabilities in solvents of different polarities. The photophys. properties of the difluoro-boradiazaindacene cores are highly sensitive towards change in polarity of microenvironments because of twisted intramol. charge transfer (TICT) characteristics. The dyes show unusually large Stokes shifts and their photophys. properties such as emission maxima and fluorescence intensity were altered to a great extent in the presence of trace amount of TFA in chloroform. These dyes can be used as promising candidates for pH probes and non-linear optical materials.
Dyes and Pigments published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is Al2H32O28S3, Quality Control of 14294-10-1.
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