Oda, Kazuaki published the artcilePhotochemistry of the nitrogen-thiocarbonyl systems. 30. Intermolecular photoaddition reaction of arenecarbothioamides to 2-methoxy- and 2-(trimethylsiloxy)furans. Facile synthesis of arene-fused aminobenzoates by novel photoinduced benzannulation, Safety of 3-Methoxybenzothioamide, the publication is Chemical & Pharmaceutical Bulletin (1997), 45(4), 584-589, database is CAplus.
Irradiation of arenecarbothioamides, e.g., 3-RC6H4C(S)NH2 (R = H, Me, OMe, cyano, NO2), with 2-methoxyfuran in benzene solution gave arene-fused aminobenzoates, e.g., I, in moderate yields accompanied by small amounts of arylpyrroles or arylthiophenes. In the case of 2-(trimethylsiloxy)furan, arenecarbothioamides gave arene-fused aminobenzoates in good yields as sole products. It was demonstrated that certain furan derivatives are potentially useful as building blocks in photoinduced benzannulation.
Chemical & Pharmaceutical Bulletin published new progress about 64559-06-4. 64559-06-4 belongs to amides-buliding-blocks, auxiliary class Amine,Benzene,Amide,Ether, name is 3-Methoxybenzothioamide, and the molecular formula is C8H9NOS, Safety of 3-Methoxybenzothioamide.
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