Bravo-Zhivotovskii, D. A. published the artcileReactions of triethylgermyllithium with N,N-dialkylated carboxamides, Related Products of amides-buliding-blocks, the publication is Journal of Organometallic Chemistry (1983), 248(1), 51-60, database is CAplus.
AcNMe2, Me3CCONMe2, F3CCONEt2 and BzNEt2 reacted with Et3GeLi, which is made from (Et3Ge)2Hg and Li in hexane, to give the corresponding acyltriethylgermanes as the principal product. The regioselectivity depends markedly on the reaction conditions and the nature of the acyl fragment of amides. Thus, Et3GeLi reacted with AcNMe2 as metalating agent to give LiCH2CONMe2 in THF. Mechanistic interpretations of these results are discussed.
Journal of Organometallic Chemistry published new progress about 360-92-9. 360-92-9 belongs to amides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Amine,Aliphatic hydrocarbon chain,Amide, name is N,N-Diethyl-2,2,2-trifluoroacetamide, and the molecular formula is C6H10F3NO, Related Products of amides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics