Pierce, Arleen C. published the artcileReactions of trihalogenated esters with triethylamine and anions, Recommanded Product: N,N-Diethyl-2,2,2-trifluoroacetamide, the publication is Journal of Organic Chemistry (1962), 3968-73, database is CAplus.
The reactions of several trihalogenated esters with triethylamine were studied at room temperature All the trihalogenated esters formed quaternary ammonium compounds with triethylamine. In the case of the trifluoro esters, the formation of N,N-diethyltrifluoroacetamide and an ether was a competing reaction. Amide formation was not observed for the tribromo and trichloro esters, at room temperature, but occurred with methyl thioltrichloroacetate. During this study it was observed that methyl trichloroacetate behaved as an alkylating agent toward sodium phenoxide, while ethyl trifluoroacetate behaved as an acylating agent. A significant feature of this work is the alkylating ability of alkyl trichloroacetates, at room temperature This property makes methyl trichloroacetate a potentially useful methylating agent to replace toxic compounds such as diazomethane or dimethyl sulfate.
Journal of Organic Chemistry published new progress about 360-92-9. 360-92-9 belongs to amides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Amine,Aliphatic hydrocarbon chain,Amide, name is N,N-Diethyl-2,2,2-trifluoroacetamide, and the molecular formula is C6H10F3NO, Recommanded Product: N,N-Diethyl-2,2,2-trifluoroacetamide.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics