Liebscher, Juergen published the artcileReaction of 3-chloroprop-2-eniminium salts with alkali rhodanides, SDS of cas: 14294-10-1, the publication is Zeitschrift fuer Chemie (1978), 18(9), 334-5, database is CAplus.
The pyrimidinethiones I (R = Ph, 4-MeC6H4, 4-MeOC6H4, 4-ClC6H4, 2-naphthyl; R1 = 4-MeOC6H4, 2-MeOC6H4, 4-MeC6H4, 2-naphthyl, 3-MeOC6H4) were obtained by treating RCCl:CHCH:N+Me2 ClO4– was alkali metal isothiocyanate and treating SCNCR:CHCH:N+Me2 ClO4– (II) with R1NH2. Treatment of II with R22NH (NR22 = morpholino, pyrrolidino, NMe2) gave the thiazinium salts III (R3 = H). Reaction of III (R = 4-MeC6H4, NR22 = NMe2, R3 = H) with PhNMe2 gave III (R = 4-MeC6H4, NR22 = NMe2, R3 = 4-Me2NC6H4).
Zeitschrift fuer Chemie published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C5H10N2OS, SDS of cas: 14294-10-1.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics