2-Mercapto-(1H)-1,3,2λ5-benzodiazaphosphorine-2,4-dithiones. Part I. Synthesis and spectral studies was written by Shinde, B. R.;Shenoy, S. J.;Pai, N. R.. And the article was included in Indian Journal of Chemistry in 1990.Application In Synthesis of N-Benzyl-2-chloro-5-nitrobenzamide The following contents are mentioned in the article:
The reaction of 2-H2NC6H4CONH2 with P2S5 in boiling pyridine leading to pyridine adduct of title compound I. The synthesis has been extended to a number of substituted anthranilamides to afford the new adducts. Newer adducts in which pyridine mol. is replaced by α- and γ-picolines and Et3N resp. have also been synthesized. 1H NMR and mass spectra of the products have been recorded and discussed. This study involved multiple reactions and reactants, such as N-Benzyl-2-chloro-5-nitrobenzamide (cas: 83909-69-7Application In Synthesis of N-Benzyl-2-chloro-5-nitrobenzamide).
N-Benzyl-2-chloro-5-nitrobenzamide (cas: 83909-69-7) belongs to amides. In primary and secondary amides, the presence of N–H dipoles allows amides to function as H-bond donors as well. Thus amides can participate in hydrogen bonding with water and other protic solvents; the oxygen atom can accept hydrogen bonds from water and the N–H hydrogen atoms can donate H-bonds. In simple aromatic amides, fragmentation occurs on both sides of the carbonyl group. If a hydrogen is available in N-substituted aromatic amides, it tends to migrate and form an aromatic amine and the loss of a ketene.Application In Synthesis of N-Benzyl-2-chloro-5-nitrobenzamide
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics