Blencowe, Anton published the artcileSynthesis of hyperbranched poly(aryl ether)s via carbene insertion processes, Category: amides-buliding-blocks, the publication is Macromolecules (2007), 40(4), 939-949, database is CAplus.
Homopolymerization of alkylaryl carbenes derived from diazirine monomers that featured benzyl alc. or phenol residues was found to lead to the production of soluble hyperbranched poly(aryl ether)s. The polymerization process was influenced by the solvents employed, monomer concentration, and the reaction time. An increase in the monomer concentration and reaction time was found to lead to an increase in the mol. weight characteristics of the resulting polymers as determined by gel permeation chromatog. (GPC). The composition and architecture of the polyethers were determined by NMR spectroscopic anal. and were found to be highly complex and dependent on the structure of the monomers used. All of the polymers were found to contain ether linkages formed via carbene insertion into O-H bonds, although polymers derived from phenolic carbenes also contained linkages arising from C-alkylation.
Macromolecules published new progress about 360-92-9. 360-92-9 belongs to amides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Amine,Aliphatic hydrocarbon chain,Amide, name is N,N-Diethyl-2,2,2-trifluoroacetamide, and the molecular formula is C6H10F3NO, Category: amides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics