Waghorne, W. Earle’s team published research in Journal of Solution Chemistry in 2020-04-30 | CAS: 123-39-7

Journal of Solution Chemistry published new progress about Basicity. 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Product Details of C2H5NO.

Waghorne, W. Earle published the artcileA Study of Kamlet-Taft β and π* Scales of Solvent Basicity and Polarity/Polarizability Using Computationally Derived Molecular Properties, Product Details of C2H5NO, the main research area is solvent basicity polarity polarizability molicualr property.

The Kamlet and Taft solvent basicity parameter, β, and solvent polarity/polarizability parameter, π*, were analyzed in terms of properties of the solvent mols. derived from computational chem. The anal. of β, using a larger data set, confirms earlier conclusions that, for aprotic solvents, the basicity is determined by the partial charge on the most neg. atom of the solvent mol. and by the energy of the highest energy MO associated with the donor site. For alcs. and nitrogen bases containing N-H moieties, the β values deviate systematically from those for the non-hydrogen bonding solvents. Anal. of the polarity/polarizability parameter, π*, shows that it depends directly on the dipole moment, and quadrupolar amplitude of the solvent and on the energy of the HOMO, but decreases linearly with increasing solvent polarizability.

Journal of Solution Chemistry published new progress about Basicity. 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Product Details of C2H5NO.

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics