Song, Jia-Lin published the artcileRh(III)-Catalyzed N-Arylation of Alkyl Dioxazolones with Arylboronic Acids for the Synthesis of N-Aryl Amides, SDS of cas: 7465-88-5, the main research area is aryl amide preparation; alkyl dioxazolone aryl heterocyclic alkenyl boronic acid arylation amination.
Herein, a method for N-aryl amides preparation has been established through Rh(III)-catalyzed C(sp2)-N cross-coupling reactions of alkyl dioxazolones with arylboronic acids, heterocyclic boronic acid, and alkenyl boronic acid. This efficient and straightforward catalytic approach was featured with broad substrate scope (38 examples), good functional group compatibility, high yields (up to 99 %), and is suitable for late-stage modification of drug mol. structures. The possible mechanism hypothesis was also accomplished.
European Journal of Organic Chemistry published new progress about Amination. 7465-88-5 belongs to class amides-buliding-blocks, name is 4-Methoxy-N-phenylbenzamide, and the molecular formula is C14H13NO2, SDS of cas: 7465-88-5.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics